Catalytic Oxidation by Means of Complex Iron
نویسندگان
چکیده
The observation of Manchot? that sodium pentacyano-ammineferroate2 I absorbs oxygen has led Baudisch and his coworkers3 to study the catalytic action of this salt, as well as of its water analogue II, in the oxidation of pyrimidines and purines. The present authors have previously reported in this journal4 on the nature of the oxidation products obtained. In the present paper the problem is considered from the standpoint of the catalyst. The work has been limited to sodium-pentacyano-ammine-ferroate I because of the ready availability of this salt in a satisfactory state of purity.
منابع مشابه
Catalytic application of an organosuperbase denderon grafted on mesoporous SBA-15 and related palladium complex in the aerobic oxidation of alcohols
An efficient synthetic method for successful synthesis of amine denderon on SBA-15 and related Pd (II) complex has been developed. This modified mesoporous material was characterized by various techniques such as TEM, XRD, atomic absorption spectroscopy, N2 adsorption-desorption, and FT-IR. The catalytic activities of the prepared catalysts were investigated by employing aerobic oxidation of al...
متن کاملSynthesis, characterisation and catalytic activity of Schiff base Cu(II) metal complex
This study reports the synthesis of chitosan anchored Schiff base, ([2-oxo-1H-indol-3-ylidene] amino) chitosan and its Cu (II) metal complex. The complex was characterized by elemental analysis, FT-IR Spectrum, thermogravimetry analysis .The crystallinity of the compound was analyzed by powder X-ray diffraction technique. The catalytic efficiency of complex was studied in the oxidation of alcoh...
متن کاملSynthesis, characterisation and catalytic activity of Schiff base Cu(II) metal complex
This study reports the synthesis of chitosan anchored Schiff base, ([2-oxo-1H-indol-3-ylidene] amino) chitosan and its Cu (II) metal complex. The complex was characterized by elemental analysis, FT-IR Spectrum, thermogravimetry analysis .The crystallinity of the compound was analyzed by powder X-ray diffraction technique. The catalytic efficiency of complex was studied in the oxidation of alcoh...
متن کاملCharacterization and Catalytic Behaviour of Nanostructured Iron Oxide Powder from Waste Pickle Liquor of Steel Industry
Nanostructured iron oxide powder that has been recovered from waste pickling liquor unit of steel industry was studied for oxidation catalytic applications. In this research, the powder was characterized by X-ray diffraction (XRD) and transition electron microscopy (TEM) for determination of phase structure, morphology and particle size. Furthermore, the specific surface area of the powder was ...
متن کاملExpedient Catalytic Access to Geraniol Epoxide Using a New Vanadium Schiff Base Complex on Modified Magnetic Nanoparticles
The Fe3O4@SiO2@APTMS@Glu-His@V complex was prepared with modification of iron oxide magnetic nanoparticles with (3-aminopropyl) trimethoxysilane (APTMS) and glutaraldehyde-L-histidine Schiff base followed by complexation with VOSO4. Characterization of the Fe3O4@SiO2@APTMS@Glu-His@V complex was carried out by means of FTIR, XRD, SEM, EDX, TEM, AAS and VSM techniques. It was found that Fe3O4@SiO...
متن کاملInvestigation of Catalytic Activity of Bis[2-(p-tolyliminomethyl)phenolato] Copper(II) Complex in the Selective Oxidation of Alcohols with Hydrogen Peroxide
In this article, the catalytic activity of bis[2-(p-tolyliminomethyl)phenolato] copper(II) complex was studied, for the first time, in the oxidation of various primary and secondary alcohols to the corresponding aldehydes or ketones. The effect of different solvent was studied in the oxidation of benzyl alcohol and methanol was chosen as the reaction medium. Also the effect of different oxidant...
متن کامل